Abstract
In this talk, I will briefly introduce my latest development in an emerging field “QED chemistry”. In the past few years, exploring chemical processes induced by vacuum electromagnetic fields has attracted considerable attention because the entry of quantum electrodynamics (QED) into chemistry is a new concept in fundamental chemistry. Quantum light can affect molecules in various aspects, and I will cover four different research topics (i) molecular fluorescence, (ii) resonance energy transfer, (iii) electron transfer, and (iv) non-adiabatic electromagnetic vacuum fluctuations. First, in the framework of macroscopic QED, I developed a unified theory of molecular fluorescence, which enables us to describe the dynamics of molecular fluorescence coupled to quantum light from weak to strong light-matter couplings in a complicated dielectric environment. Based on this theory, we derived a parameter-free formula which can be used to estimate the exciton-polariton coupling for single molecules in a nanostructure. Our theory is in good agreement with the reported experimental results [Chikkaraddy et al., Nature 2016, 535, 127-130]. Second, I developed a unified theory of radiative and non-radiative resonance energy transfer based on macroscopic QED. The proposed theory allows us to describe longrange resonance energy transfer between two entities in spatially dependent vacuum electric fields. Third, we generalized famous Marcus theory and developed a theory of electron transfer based on conventional QED. Our theory shows that QED effects can significantly enhance the kinetic rate of electron transfer reactions by several orders of magnitude in the absence of cavities, which is implicitly supported by experimental reports. Fourth, we generalized the internal conversion theory at the first level in the framework of cavity QED by including the effects of non-adiabatic electromagnetic vacuum fluctuations. Our theory shows that, even without strong light-matter coupling, non-adiabatic QED effects can significantly influence the internal conversion rates.