Probing matters through diamond windows

Prof. Sean Shieh from Department of Earth Sciences, Western University, Canada

@ CCMS/PHYSICS BUILDING R212

A great number of matters behave dramatically different from what we know at ambient

conditions when they are subjected to extreme pressure and temperature conditions. For

example, water can transform to ice at low pressure and room temperature. Similarly, carbon

dioxide (dry ice) becomes molecular solid at <1 GPa and 300 K. When pressure greater than 10

GPa, it transforms to orthorhombic structure. Further compression to above 37-50 GPa, carbon

dioxide lose its long-range order and become non-molecular solids. Under high pressure oxides

may change their colors and close their band gaps. Furthermore, charge transfer may also occur

in responding to the new extreme environment, such as TlReO4 and TmTe.

In this talk, I will introduce the high pressure diamond-anvil cell apparatus and its applications to

structure determinations and thermodynamic and physical properties (stress, elasticity)

measurements using Raman, IR and synchrotron X-ray.

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